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Preface; Contents; About the Authors; Chapter 1: The Carbon Dioxide Molecule; 1.1 Introduction; 1.2 Electronic Properties of CO2; 1.2.1 Ground State of Carbon Dioxide; 1.2.2 Lowest Excited States of Carbon Dioxide; 1.3 Main Features of Carbon Dioxide Reactivity; 1.3.1 Carbon Dioxide as O-Nucleophile; 1.3.2 Carbon Dioxide as C-Electrophile; 1.3.3 Amphoteric Reactivity of Carbon Dioxide; 1.4 Carbon Dioxide Radical Anion, CO2-; 1.5 Carbon Dioxide Radical Cation, CO2+; 1.6 Spectroscopic Techniques Applied to the CO2 States; 1.6.1 IR Spectroscopy; 1.6.2 UV Spectrum of Carbon Dioxide.
1.6.3 Nuclear Magnetic Resonance (NMR) SpectroscopyReferences; Chapter 2: CO2 Coordination to Metal Centres: Modes of Bonding and Reactivity; 2.1 Mode of Bonding of Carbon Dioxide to Transition-Metal Centres; 2.2 XRD Structure of eta2-C, O Mononuclear Metal Complexes; 2.3 XRD Structural Data for eta1-C Metal Complexes; 2.4 XRD Structural Characterization of O-End-On Complexes; 2.5 Multinuclear Complexes; 2.5.1 Side-On Bonded Complexes; 2.5.2 O-End-On Bonded Complexes; 2.6 Spectroscopic (IR and 13C-NMR) Data for the Complexes Correlated to the Various Modes of Bonding of CO2.
2.6.1 Infrared Data Relevant to Transition Metal Complexes2.6.2 NMR Data for Transition Metal Complexes; 2.7 Fluxionality of the CO2 Molecule Coordinated to Transition Metal Systems; 2.8 Interaction of CO2 with Metal Atoms in Low-Temperature Solid-Inert-Gas Matrices; 2.9 Interaction of Metal Cations with CO2 in the Gas Phase; 2.10 Reactions of Coordinated CO2; 2.10.1 Reaction of Coordinated CO2 with Electrophiles and O-Transfer from CO2 to Produce CO; 2.10.2 Reactions of Coordinated CO2 with Nucleophiles; 2.11 Conclusions; References; Chapter 3: Interaction of CO2 with Electron-Rich Moieties.
3.1 Reaction with the Hydride Ion3.2 Reaction with Hydroxide and Alkoxide Species; 3.3 Reaction with Carbanions; 3.4 Reaction with Amines; References; Chapter 4: Insertion of CO2 into E-X Bonds; 4.1 Carbon Dioxide Insertion into M-H Bonds; 4.2 CO2 Insertion into M-OH Bonds; 4.3 CO2 Insertion into M-C Bonds; 4.4 CO2 Insertion into M-OR Bonds; 4.5 Insertion into M-O2 Bonds; 4.6 CO2 Insertion into M-N Bonds; 4.6.1 Insertion into Transition Metal Amides; 4.6.2 Insertion into Main Group and Post-Transition Metal Amides; 4.6.3 Insertion into Amides of Non-Metallic Elements.
4.7 CO2 Insertion into M-P Bonds4.8 CO2 Insertion into C-C Bonds; 4.9 CO2 Insertion into C-N Bonds; 4.10 Insertion into Other E-X Bonds; 4.10.1 Insertion into M-M Bonds; 4.10.2 Insertion into Si-H Bonds; 4.10.3 Insertion into C-H Bonds; 4.11 Conclusions; References; Chapter 5: Interaction of CO2 with C-C Multiple Bonds; 5.1 Introduction; 5.2 Oxidative Coupling with CO2; 5.3 Carboxylation of Olefins; 5.4 Carboxylation of Alkynes; 5.5 Carboxylation of Allenes; 5.6 Carboxylation of Conjugated Dienes; References.
1.6.3 Nuclear Magnetic Resonance (NMR) SpectroscopyReferences; Chapter 2: CO2 Coordination to Metal Centres: Modes of Bonding and Reactivity; 2.1 Mode of Bonding of Carbon Dioxide to Transition-Metal Centres; 2.2 XRD Structure of eta2-C, O Mononuclear Metal Complexes; 2.3 XRD Structural Data for eta1-C Metal Complexes; 2.4 XRD Structural Characterization of O-End-On Complexes; 2.5 Multinuclear Complexes; 2.5.1 Side-On Bonded Complexes; 2.5.2 O-End-On Bonded Complexes; 2.6 Spectroscopic (IR and 13C-NMR) Data for the Complexes Correlated to the Various Modes of Bonding of CO2.
2.6.1 Infrared Data Relevant to Transition Metal Complexes2.6.2 NMR Data for Transition Metal Complexes; 2.7 Fluxionality of the CO2 Molecule Coordinated to Transition Metal Systems; 2.8 Interaction of CO2 with Metal Atoms in Low-Temperature Solid-Inert-Gas Matrices; 2.9 Interaction of Metal Cations with CO2 in the Gas Phase; 2.10 Reactions of Coordinated CO2; 2.10.1 Reaction of Coordinated CO2 with Electrophiles and O-Transfer from CO2 to Produce CO; 2.10.2 Reactions of Coordinated CO2 with Nucleophiles; 2.11 Conclusions; References; Chapter 3: Interaction of CO2 with Electron-Rich Moieties.
3.1 Reaction with the Hydride Ion3.2 Reaction with Hydroxide and Alkoxide Species; 3.3 Reaction with Carbanions; 3.4 Reaction with Amines; References; Chapter 4: Insertion of CO2 into E-X Bonds; 4.1 Carbon Dioxide Insertion into M-H Bonds; 4.2 CO2 Insertion into M-OH Bonds; 4.3 CO2 Insertion into M-C Bonds; 4.4 CO2 Insertion into M-OR Bonds; 4.5 Insertion into M-O2 Bonds; 4.6 CO2 Insertion into M-N Bonds; 4.6.1 Insertion into Transition Metal Amides; 4.6.2 Insertion into Main Group and Post-Transition Metal Amides; 4.6.3 Insertion into Amides of Non-Metallic Elements.
4.7 CO2 Insertion into M-P Bonds4.8 CO2 Insertion into C-C Bonds; 4.9 CO2 Insertion into C-N Bonds; 4.10 Insertion into Other E-X Bonds; 4.10.1 Insertion into M-M Bonds; 4.10.2 Insertion into Si-H Bonds; 4.10.3 Insertion into C-H Bonds; 4.11 Conclusions; References; Chapter 5: Interaction of CO2 with C-C Multiple Bonds; 5.1 Introduction; 5.2 Oxidative Coupling with CO2; 5.3 Carboxylation of Olefins; 5.4 Carboxylation of Alkynes; 5.5 Carboxylation of Allenes; 5.6 Carboxylation of Conjugated Dienes; References.