Linked e-resources
Details
Table of Contents
Intro; Contents; 1 Introduction; 1.1 The Paris Agreement; 1.2 CO2 Capture and Storage; 1.3 CO2-Capture Methods; References; 2 Chemistry of Amine-Based CO2 Capture; 2.1 Amines for CO2 Capture; 2.2 Classification of Amines; 2.3 Boiling Point and Viscosity; 2.4 Activity and Concentration; 2.5 Basicity of Amines; 2.5.1 Definition of Base; 2.5.2 Amine pKa; 2.5.3 Comparison of Amine with Water; 2.6 Carbamate and Bicarbonate Formations; 2.6.1 Carbamate Stability; 2.6.2 Ratio of Carbamate to Bicarbonate; 2.6.3 Kinetics of Carbamate and Bicarbonate Formations
2.7 Other Species Formed by Amine-CO2 Reaction2.7.1 Carbamic Acid; 2.7.2 Alkyl Carbonate; 2.8 Mechanism of Amine-CO2 Reaction; 2.8.1 Zwitterion Mechanism; 2.8.2 Carbamic Acid Mechanism; 2.8.3 Single-Step Termolecular Mechanism; 2.8.4 Base-Catalyzed Hydration; 2.8.5 Interconversion of Carbamate and Bicarbonate; 2.9 Effect of Reaction Field; 2.10 Conclusion; References; 3 CO2 Capture with Absorbents; 3.1 Absorption; 3.1.1 Physical Absorption; 3.1.2 Chemical Absorption; 3.2 Process Flows of Chemical Absorption; 3.2.1 Atmospheric Pressure Gas (Post-combustion CO2 Capture)
3.2.2 Pressurized Gas (Pre-combustion CO2 Capture)3.3 CO2 Capture for CCS; 3.3.1 Power Sector; 3.3.2 Industry Sector; 3.4 Research and Development; 3.5 State-of-the-Art Technology; 3.5.1 Development of New Solvents; 3.5.2 Results in Laboratory Stage; 3.5.3 Scale-up and Demonstration; 3.5.4 Outcomes; 3.6 Exploring New Research Area; 3.6.1 Chemical Absorption with High-Pressure Regeneration; 3.6.2 Novel Absorbents for High-Pressure Regeneration; 3.7 Conclusion; References; 4 CO2 Capture with Adsorbents; 4.1 Outline of Adsorption Separation Method; 4.1.1 Introduction
4.1.2 Adsorption Separation Method4.1.3 CO2 Separation and Recovery Technology by Physical Adsorption Method; 4.2 CO2 Separation and Recovery Technology by Chemical Adsorption Method Using Mesoporous Material; 4.3 Recent Development of CO2-Adsorption Separation Method; 4.4 New CO2-Adsorption Separation Technology Development at RITE; 4.4.1 Amine-Grafted Mesoporous Silica; 4.4.2 Amine-Impregnated Solid Sorbent; 4.5 Summary and Future Prospects; References; 5 Membrane for CO2 Separation; 5.1 Membrane Separation Technology for CO2 Separation; 5.1.1 Polymeric Membrane; 5.1.2 Inorganic Membrane
5.1.3 Ionic Liquid Membrane5.1.4 Facilitated Transport Membrane; 5.2 Development of "Molecular Gate" Membrane; 5.2.1 Development of Commercial-Sized Dendrimer Composite Membrane Modules by In Situ Coating for CO2 Removal from Flue Gas; 5.2.2 Development of Poly(amidoamine) Dendrimer/Polymer Hybrid Membrane Modules for CO2 Removal from IGCC; 5.3 R&D Project for CO2 Removal from IGCC Plant; 5.3.1 Membrane Preparation; 5.3.2 Gas Permeation Performances; 5.3.3 Fabrication of Membrane Elements; 5.4 Summary; References
2.7 Other Species Formed by Amine-CO2 Reaction2.7.1 Carbamic Acid; 2.7.2 Alkyl Carbonate; 2.8 Mechanism of Amine-CO2 Reaction; 2.8.1 Zwitterion Mechanism; 2.8.2 Carbamic Acid Mechanism; 2.8.3 Single-Step Termolecular Mechanism; 2.8.4 Base-Catalyzed Hydration; 2.8.5 Interconversion of Carbamate and Bicarbonate; 2.9 Effect of Reaction Field; 2.10 Conclusion; References; 3 CO2 Capture with Absorbents; 3.1 Absorption; 3.1.1 Physical Absorption; 3.1.2 Chemical Absorption; 3.2 Process Flows of Chemical Absorption; 3.2.1 Atmospheric Pressure Gas (Post-combustion CO2 Capture)
3.2.2 Pressurized Gas (Pre-combustion CO2 Capture)3.3 CO2 Capture for CCS; 3.3.1 Power Sector; 3.3.2 Industry Sector; 3.4 Research and Development; 3.5 State-of-the-Art Technology; 3.5.1 Development of New Solvents; 3.5.2 Results in Laboratory Stage; 3.5.3 Scale-up and Demonstration; 3.5.4 Outcomes; 3.6 Exploring New Research Area; 3.6.1 Chemical Absorption with High-Pressure Regeneration; 3.6.2 Novel Absorbents for High-Pressure Regeneration; 3.7 Conclusion; References; 4 CO2 Capture with Adsorbents; 4.1 Outline of Adsorption Separation Method; 4.1.1 Introduction
4.1.2 Adsorption Separation Method4.1.3 CO2 Separation and Recovery Technology by Physical Adsorption Method; 4.2 CO2 Separation and Recovery Technology by Chemical Adsorption Method Using Mesoporous Material; 4.3 Recent Development of CO2-Adsorption Separation Method; 4.4 New CO2-Adsorption Separation Technology Development at RITE; 4.4.1 Amine-Grafted Mesoporous Silica; 4.4.2 Amine-Impregnated Solid Sorbent; 4.5 Summary and Future Prospects; References; 5 Membrane for CO2 Separation; 5.1 Membrane Separation Technology for CO2 Separation; 5.1.1 Polymeric Membrane; 5.1.2 Inorganic Membrane
5.1.3 Ionic Liquid Membrane5.1.4 Facilitated Transport Membrane; 5.2 Development of "Molecular Gate" Membrane; 5.2.1 Development of Commercial-Sized Dendrimer Composite Membrane Modules by In Situ Coating for CO2 Removal from Flue Gas; 5.2.2 Development of Poly(amidoamine) Dendrimer/Polymer Hybrid Membrane Modules for CO2 Removal from IGCC; 5.3 R&D Project for CO2 Removal from IGCC Plant; 5.3.1 Membrane Preparation; 5.3.2 Gas Permeation Performances; 5.3.3 Fabrication of Membrane Elements; 5.4 Summary; References