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Title
Synthesis of optically active oxymethylenehelicene oligomers and self-assembly phenomena at a liquid-solid interface / by Tsukasa Sawato.
ISBN
9789811531927 (electronic book)
9811531927 (electronic book)
9789811531910
Published
Singapore : Springer, 2020.
Language
English
Description
1 online resource (xii, 83 pages) : illustrations.
Item Number
10.1007/978-981-15-3
Call Number
QD382.O43
Dewey Decimal Classification
541/.39
Summary
In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid-solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid-solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid-solid interfaces not found in solutions. Detailed results are provided for new chemical reactions at liquid-solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid-solid interface.
Note
"Doctoral thesis accepted by Tohoku University, Sendai, Japan."
Bibliography, etc. Note
Includes bibliographical references.
Access Note
Access limited to authorized users.
Series
Springer theses.
1. Introduction
2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid-Solid Interface
3. Mechanical Stirring Induces Heteroaggregate Formation and Self-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution
4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers
5. Conclusions
6. Experimental Section.
