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Phase Behavior of Two-Dimensional Water Confined in Graphene Nanocapillaries / by YinBo Zhu.

Zhu, YinBo. author.
2020
TA349-359
Available Online
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Title
Phase Behavior of Two-Dimensional Water Confined in Graphene Nanocapillaries / by YinBo Zhu.
Author
Zhu, YinBo. author.
Edition
1st ed. 2020.
ISBN
9811579571
9789811579578
9811579563
9789811579561
DOI
https://doi.org/10.1007/978-981-15-7957-8
Published
Singapore : Springer Singapore : Imprint: Springer, 2020.
Language
English
Description
1 online resource (XVII, 118 pages) : illustrations.
Item Number
10.1007/978-981-15-7957-8 doi
Call Number
TA349-359
Dewey Decimal Classification
531
Summary
In this book, the authors use molecular dynamics simulations to conduct a comprehensive study of the compression/superheating limit and phase transition of 2D (monolayer, bilayer, and trilayer) water/ice constrained in graphene nanocapillaries. When subjected to nanoscale confinement and under ultrahigh pressure, water and ice behave quite differently than their bulk counterparts, partly because the van der Waals pressure can spark a water-to-ice transformation, known as the metastability limit of two-dimensional (2D) liquids. From a mechanical standpoint, this liquid-to-solid transformation characterizes the compression limit (or metastability limit) of 2D water. The findings presented here could help us to better understand the phase behavior of 2D confined water/ice.
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Series
Springer Theses, Recognizing Outstanding Ph.D. Research, 2190-5053
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Introduction
Monolayer square-like ice between two graphene sheets
Superheating of monolayer ice in graphene nanocapillaries
AB-stacking bilayer square-like ice in graphene nanocapillaries
AA-stacking bilayer ice in graphene nanocapillaries
Trilayer ice in graphene nanocapillaries
Compression limit of 2D water confined in graphene nanocapillaries
Summary and future work
Appendix A: Mechanical design on graphene-based materials.

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