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Title
Development of synthetic methods for novel photofunctional multinuclear complexes : simple synthetic methods for multinuclear complexes using various C-C coupling reactions / Yasuomi Yamazaki.
ISBN
9789811671487 (electronic bk.)
9811671486 (electronic bk.)
9811671478
9789811671470
Publication Details
Singapore : Springer, [2022]
Language
English
Description
1 online resource
Item Number
10.1007/978-981-16-7148-7 doi
Call Number
QD602
Dewey Decimal Classification
541/.35
Summary
This book presents several helpful synthetic methods for diverse multinuclear complexes. The results described can be used to selectively connect mononuclear as well as multinuclear complexes with other metal complexes to construct valuable photofunctional compounds. Using the new synthetic methods, it was possible to selectively connect several types of metal complexes in a single step under relatively mild reaction conditions. This so-called building block approach utilizes various C-coupling reactions between metal complexes with functional groups as active moieties. Owing to the large pi-conjugation systems, the multinuclear complexes synthesized using coupling reactions showed a strong absorption ability over a wide range of visible light and long emission lifetimes, which are ideal properties for photosensitizers and light absorbers. By combining these coupling methods with the newly developed hydrogenation reactions, the binding mode of the linkers in multinuclear complexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and photosensitizers, and in light-harvesting systems. The synthetic methods and strategies presented in this book diversify not only the structures but also functions of multinuclear complexes.
Note
"Doctoral Thesis accepted by Tokyo Institute of Technology, Tokyo, Japan."
Bibliography, etc. Note
Includes bibliographical references.
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Access limited to authorized users.
Digital File Characteristics
text file
PDF
Source of Description
Online resource; title from PDF title page (SpringerLink, viewed November 18, 2021).
Series
Springer theses, 2190-5061
General Introduction
Synthesis of Multinuclear Complexes Using the Mizoroki-Heck reaction
Selective Synthesis of Various Photofunctional Multinuclear Complexes Using Combination of the Mizoroki-Heck Reaction and the Homo-coupling Reaction
Photochemical and Electrochemical Hydrogenation of Pi Conjugated Bridging Ligands on Photofunctional Multinuclear Complexes
Synthesis of Novel Multinuclear Complexes for Light-harvesting Systems Using the Coupling Reactions with Ring-shaped Multinuclear Re(I) Complexes as Building Blocks
Conclusions.
