Catalytic and process study of the selective hydrogenation of acetylene and 1,3-butadiene / Ruijun Hou.
Hou, Ruijun, author.
2017
QD281.H8
Available Online

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Title Catalytic and process study of the selective hydrogenation of acetylene and 1,3-butadiene / Ruijun Hou.
Author Hou, Ruijun, author.
ISBN 9789811007736 (electronic book)
981100773X (electronic book)
9789811007729
9811007721
DOI https://doi.org/10.1007/978-981-10-0773-6
Published Singapore : Springer, 2017.
Language English
Description 1 online resource (xii, 141 pages) : color illustrations.
Item Number 10.1007/978-981-10-0773-6 doi
Call Number QD281.H8
Dewey Decimal Classification 547/.23
Summary This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<.
Note "Doctoral thesis accepted by Tsinghua University, Beijing, China."
Bibliography, etc. Note Includes bibliographical references.
Access Note Access limited to authorized users.
Digital File Characteristics text file PDF
Source of Description Online resource; title from PDF title page (viewed February 6, 2017)
Series Springer theses.
Available in Other Form Print version: 9789811007729
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Record Appears in Online Resources > Ebooks
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Introduction
Experimental and Theoretical Methods
Design of Pd-Ni Bimetallic Catalyst
Effect of Oxide Supports on Pd–Ni Bimetallic Catalysts
Replacing Precious Metals with Carbide Catalysts
Liquid Phase Hydrogenation of Acetylene
Conclusion.

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