Unlimited

Authorized users

Can lend chapters, not whole ebooks

Copper(I)-catalyzed stereoselective borylation reactions : multisubstituted alkenyl and allylic boronates / Yu Ozawa.

9789819910984 electronic book
9819910986 electronic book
9789819910977 print
9819910978 print

Singapore : Springer, [2023]

English

1 online resource (xiii, 226 pages) : illustrations (some color).

10.1007/978-981-99-1098-4 doi

QD412.B1 O93 2023

547/.05671

This book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanisms are analyzed with state-of-the-art DFT and other computational methods. In this book, the author synthesizes some multi-substituted alkenyl and allylic boronates via borylation reactions using a copper(I)/diboron catalyst system. Those compounds contain novel densely substituted and distorted structures, which have not been accessed by other methods. The high stereoselectivities are achieved by the optimization of the catalyst, especially the ligand. Some new ligands are also developed in this book. Furthermore, the derivatization of the borylation products is demonstrated to access the sterically demanding complex molecules. Also, the author performs computational analysis to reveal how the catalyst controls the selectivities. The deep insight into the reaction mechanism provides guides for rational catalyst design for not only copper(I) catalysis but also other transition metal catalysis. Thus, the content should be of interest to academic and industrial scientists in a wide range of areas.

"Doctoral thesis accepted by Hokkaido University, Sapporo, Japan."

Includes bibliographical references.

Access limited to authorized users.

Description based on online resource; title from digital title page (viewed on May 26, 2023).

Springer theses.

Print version: 9789819910977

Online Resources > Ebooks
All Resources