New synthetic routes to polyoxometalate containing ionic liquids [electronic resource] : an investigation of their properties / Sven Herrmann ; foreword by Prof Dr. Carsten Steb.
2015
QD474 .H47 2015eb
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Title
New synthetic routes to polyoxometalate containing ionic liquids [electronic resource] : an investigation of their properties / Sven Herrmann ; foreword by Prof Dr. Carsten Steb.
Author
ISBN
9783658087968 electronic book
365808796X electronic book
9783658087951
365808796X electronic book
9783658087951
Published
Wiesbaden : Springer Spektrum, [2015]
Copyright
©2015
Language
English
Description
1 online resource : illustrations.
Item Number
10.1007/978-3-658-08796-8 doi
Call Number
QD474 .H47 2015eb
Dewey Decimal Classification
541.2242
Summary
In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and M©œ©ℓbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials. ℗ℓContents Polyoxometlates and Ionic Liquids in General POM-Ils as New Class of Compounds Synthesis and Characterization of POM-ILs Reactivity Towards Azide and Carbonmonoxide ℗ℓTarget Groups Researchers and students in the field of chemistry Practitioners in this area ℗ℓThe Author Sven Herrmann obtained his Masters degree at the University of Erlangen-N©ơrnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs).
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Includes bibliographical references.
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Description based on online resource; title from PDF title page (viewed February 18, 2015).
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BestMasters.
Available in Other Form
Print version: 9783658087951
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Table of Contents
Polyoxometlates and Ionic Liquids in General
POM-Ils as New Class of Compounds
Synthesis and Characterization of POM-ILs
Reactivity Towards Azide and Carbonmonoxide.
POM-Ils as New Class of Compounds
Synthesis and Characterization of POM-ILs
Reactivity Towards Azide and Carbonmonoxide.