Group 2 mediated dehydrocoupling [electronic resource] / David J. Liptrot.
2016
QD172.T6
Linked e-resources
Linked Resource
Online Access
Concurrent users
Unlimited
Authorized users
Authorized users
Document Delivery Supplied
Can lend chapters, not whole ebooks
Details
Title
Group 2 mediated dehydrocoupling [electronic resource] / David J. Liptrot.
Author
Liptrot, David J., author.
ISBN
9783319210360 (electronic book)
331921036X (electronic book)
9783319210353
331921036X (electronic book)
9783319210353
Published
Cham : Springer, [2016]
Copyright
©2016
Language
English
Description
1 online resource.
Item Number
10.1007/978-3-319-21036-0 doi
Call Number
QD172.T6
Dewey Decimal Classification
546/.3
Summary
This book presents an in-depth study into the utility of ℓℓ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner.℗ℓ Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with ℓℓ-bond metathesis allows a novel hydrogen release from silanes.
Note
"Doctoral thesis accepted by the University of Bath, UK"--t.p.
Bibliography, etc. Note
Includes references.
Access Note
Access limited to authorized users.
Source of Description
Online resource; title from PDF title page (viewed July 31, 2015)
Series
Springer theses.
Available in Other Form
Print version: 9783319210353
Linked Resources
Online Access
Record Appears in
Online Resources > Ebooks
All Resources
All Resources
Table of Contents
Introduction
Group 1-Group 2 Bimetallic Alkyls and Hydrides
Silicon-nitrogen Dehydrocoupling
Boron-nitrogen Dehydrocoupling
Single Electron Transfer Steps in Group 2 Catalysis
Summary
Future Work.
Group 1-Group 2 Bimetallic Alkyls and Hydrides
Silicon-nitrogen Dehydrocoupling
Boron-nitrogen Dehydrocoupling
Single Electron Transfer Steps in Group 2 Catalysis
Summary
Future Work.